From a quick google search found this at: http://www.w8ji.com/battery_and_charging_system.htm to charge the battery, the alternator voltage output has to exceed a minimum charging voltage. This minimum charging voltage is 13.8 volts dc across the battery terminals, or at the output of the alternator. A single lead-acid cell starts to charge at anything over 2.25 volts. Since a 12 volt battery has six cells, any 12 volt lead-acid battery needs at least 13.8 volts to start to charge. This voltage will be enough to fully charge or maintain the battery on a trickle charge, but charging time will be very long at 13.8 volts.To fully charge in reasonable times, alternator output must be 14.2 V to 14.5 V as measured right across the battery posts. Above 14.5 volts charging voltage, batteries have a greatly increased tendency to release excessive acidic vapors, hydrogen gas, and to corrode things around the battery. The battery terminal charging voltage must be less than 14.7 volts to prevent excessive gassing. Charging voltages over 14.7 volts can prematurely dry the battery by boiling out electrolyte, and increase risk of a battery hydrogen gas explosion.