We have had this problem on several timing belt jobs at the shop. It has gotten to the point where we tell customers it may break when removing it. They are a brittle metal and they are not cheap to replace either.
Can you get the woodruff key out? The last time I had a stuck gear, I soaked it with PB Blaster. I then put the transmission in gear and placed a prybar on the gear teeth and tapped the gear so it slowly rotated on the crank. I tapped it and rotated it the other way and eventually broke it loose and saved the gear.
Good luck though. They can be a royal PITA.